Crystal structure of bis(azido-κN)bis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ2N2,N3]nickel(II)
Identifieur interne : 000050 ( Main/Exploration ); précédent : 000049; suivant : 000051Crystal structure of bis(azido-κN)bis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ2N2,N3]nickel(II)
Auteurs : Abdelhakim Laachir [Maroc] ; Fouad Bentiss [Maroc] ; Salaheddine Guesmi [Maroc] ; Mohamed Saadi [Maroc] ; Lahcen El Ammari [Maroc]Source :
- Acta Crystallographica Section E: Crystallographic Communications [ 2056-9890 ] ; 2015.
Abstract
Reaction of 2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole and sodium azide with nickel(II) triflate yielded the mononuclear title complex, [Ni(N3)2(C12H8N4S)2]. The NiII ion is located on a centre of symmetry and is octahedrally coordinated by four N atoms of the two bidentate heterocyclic ligands in the equatorial plane. The axial positions are occupied by the N atoms of two almost linear azide ions [N—N—N = 178.8 (2)°]. The thiadiazole and pyridine rings of the heterocyclic ligand are almost coplanar, with a maximum deviation from the mean plane of 0.0802 (9) Å. The cohesion of the crystal structure is ensured by π–π interactions between parallel pyridine rings of neighbouring molecules [centroid-to-centroid distance = 3.6413 (14) Å], leading to a layered arrangement of the molecules parallel to (001).
Url:
DOI: 10.1107/S2056989015000201
PubMed: 25878837
PubMed Central: 4384553
Affiliations:
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Le document en format XML
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Crystal structure of bis(azido-κ<italic>N</italic>
)bis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ<sup>2</sup>
<italic>N</italic>
<sup>2</sup>
,<italic>N</italic>
<sup>3</sup>
]nickel(II)</title>
<author><name sortKey="Laachir, Abdelhakim" sort="Laachir, Abdelhakim" uniqKey="Laachir A" first="Abdelhakim" last="Laachir">Abdelhakim Laachir</name>
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</nlm:aff>
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<front><div type="abstract" xml:lang="en"><p>Reaction of 2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole and sodium azide with nickel(II) triflate yielded the mononuclear title complex, [Ni(N<sub>3</sub>
)<sub>2</sub>
(C<sub>12</sub>
H<sub>8</sub>
N<sub>4</sub>
S)<sub>2</sub>
]. The Ni<sup>II</sup>
ion is located on a centre of symmetry and is octahedrally coordinated by four N atoms of the two bidentate heterocyclic ligands in the equatorial plane. The axial positions are occupied by the N atoms of two almost linear azide ions [N—N—N = 178.8 (2)°]. The thiadiazole and pyridine rings of the heterocyclic ligand are almost coplanar, with a maximum deviation from the mean plane of 0.0802 (9) Å. The cohesion of the crystal structure is ensured by π–π interactions between parallel pyridine rings of neighbouring molecules [centroid-to-centroid distance = 3.6413 (14) Å], leading to a layered arrangement of the molecules parallel to (001).</p>
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